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Thermal ionization
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Everything about Thermal Ionisation totally explained

In thermal ionization, also referred to as surface ionization, chemically-purified material loaded onto a filament which is then heated to cause some of the material to be ionized as it boils off the hot filament. Filaments are generally flat pieces of metal around 1-2mm wide, 0.1mm thick, bent into an upside-down U shape and welded to steel posts that supply a current.

Saha-Langmuir equation

The likelihood of ionisation is a function of the filament temperature, the work function of the filament substrate and the ionization energy of the element.
   This is summarised in the Saha-Langmuir equation:
» frac = statistical weights of ion and neutral states

» :phi = surface work function

» :IP = element ionization potential

» :k = Boltzmann's constant

» :T = surface temperature

Thermal ionization mass spectrometry

One application of thermal ionization is thermal ionization mass spectrometry (TIMS). The ions being produced at the filament are directed into a mass spectrometer to analyze the elements or isotopes present in the sample.

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