Everything about Thermal Ionisation totally explained
In
thermal ionization, also referred to as
surface ionization, chemically-purified material loaded onto a
filament which is then heated to cause some of the material to be
ionized as it boils off the hot filament. Filaments are generally flat pieces of metal around 1-2mm wide, 0.1mm thick, bent into an upside-down U shape and welded to steel posts that supply a current.
Saha-Langmuir equation
The likelihood of ionisation is a function of the filament temperature, the
work function of the filament substrate and the
ionization energy of the
element.
This is summarised in the
Saha-
Langmuir equation:
» = statistical weights of ion and neutral states
» :
= surface
work function
» :IP = element
ionization potential
» :k =
Boltzmann's constant
» :T = surface temperature
Thermal ionization mass spectrometry
One application of thermal ionization is thermal ionization mass spectrometry (TIMS). The ions being produced at the filament are directed into a
mass spectrometer to analyze the elements or isotopes present in the sample.
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